A CO32−-containing, dimanganese-substituted silicotungstate trimer, K9[H14{SiW10MnIIMnIIIO38}3(CO3)]·39H2O

Ling Yang; Qisen Liu; Pengtao Ma; Jingyang Niu; Jingping Wang

doi:10.1039/C5DT00262A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A CO₃²⁻-containing, dimanganese-substituted silicotungstate trimer, K₉[H₁₄{SiW₁₀Mn^IIMn^IIIO₃₈}₃(CO₃)]·39H₂O†

Ling Yang,^a Qisen Liu,^a Pengtao Ma,^a Jingyang Niu*^a and Jingping Wang*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: (+86) 371-23886876

Abstract

An unprecedented silicotungstate trimer K₉[H₁₄{SiW₁₀Mn^IIMn^IIIO₃₈}₃(CO₃)]·39H₂O (1) has been successfully synthesized, in which the CO₃²⁻ resides inside the three Keggin {SiW₁₀Mn^IIMn^IIIO₃₈} units and the three O atoms serve as μ₂-O atoms to connect with three Mn^III. Magnetic investigation indicates that 1 exhibits antiferromagnetic coupling.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C5DT00262A
Article type: Communication
Submitted: 20 Jan 2015
Accepted: 25 Jun 2015
First published: 26 Jun 2015

Download Citation

Dalton Trans., 2015,44, 13469-13472

Permissions

Request permissions

A CO₃²⁻-containing, dimanganese-substituted silicotungstate trimer, K₉[H₁₄{SiW₁₀Mn^IIMn^IIIO₃₈}₃(CO₃)]·39H₂O

L. Yang, Q. Liu, P. Ma, J. Niu and J. Wang, Dalton Trans., 2015, 44, 13469 DOI: 10.1039/C5DT00262A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions