Issue 27, 2015

Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

Abstract

Two cobalt compounds, Cp*Co(CO)I2 (1) and CpCo(CO)I2 (2) (Cp* = η5-C5Me5, Cp = η5-C5H5), catalyze the dehydrogenation of ammonia borane under either anaerobic or aerobic conditions and are also effective hydrogenation catalysts for alkenes and alkynes using ammonia borane as a hydrogen source, also in the presence of air.

Graphical abstract: Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

Supplementary files

Article information

Article type
Communication
Submitted
09 Jan 2015
Accepted
24 Feb 2015
First published
25 Feb 2015

Dalton Trans., 2015,44, 12074-12077

Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

J. K. Pagano, J. P. W. Stelmach and R. Waterman, Dalton Trans., 2015, 44, 12074 DOI: 10.1039/C5DT00108K

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