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Issue 10, 2015
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Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

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Abstract

A general synthetic route to water-soluble PEG-supported organotrifluoroborates has been developed. In the presence of air and catalytic amounts of Pd(OAc)2, the PEG-supported organotrifluoroborates undergo homo-coupling reactions smoothly at room temperature. No additional oxidizing agent, base, or phosphine ligands are required.

Graphical abstract: Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

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Publication details

The article was received on 13 Nov 2014, accepted on 02 Feb 2015 and first published on 02 Feb 2015


Article type: Paper
DOI: 10.1039/C4DT03492A
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 4759-4764
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    Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

    L. Yong, M. Yao, D. W. Blevins and G. W. Kabalka, Dalton Trans., 2015, 44, 4759
    DOI: 10.1039/C4DT03492A

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