Issue 7, 2015
From the journal:

Dalton Transactions

Divalent ytterbium complexes with crown and heterocrown ethers†‡

Philip N. Bartlett,a   Martin J. D. Champion,a   Mark. E. Light,a   William Levason,*a   Gillian Reida  and  Peter W. Richardsona  

* Corresponding authors

a School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK
E-mail: wxl@soton.ac.uk

Abstract

Several unusual complexes of ytterbium(II) stabilised by coordination to mixed O4X2-donor macrocyclic ligands (X = O, NH, S or Se) are described. Distorted 8-coordination is evident from the crystal structure of the neutral [YbI2([18]aneO4Se2)], forming the first reported example of Yb(II)-selenoether coordination.

Graphical abstract: Divalent ytterbium complexes with crown and heterocrown ethers

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Article information

DOI
https://doi.org/10.1039/C4DT03462G
Article type
Communication
Submitted
11 Nov 2014
Accepted
01 Dec 2014
First published
02 Dec 2014
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 2953-2955

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Divalent ytterbium complexes with crown and heterocrown ethers

P. N. Bartlett, M. J. D. Champion, Mark. E. Light, W. Levason, G. Reid and P. W. Richardson, Dalton Trans., 2015, 44, 2953 DOI: 10.1039/C4DT03462G

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