Issue 3, 2015

[Cp*Ru]-catalyzed selective coupling/hydrogenation

Abstract

Access to 3,4- and 3,5-disubstituted piperidine derivatives has been achieved through [Cp*Ru]-catalyzed intermolecular coupling of allylic alcohols and propargylic amides. Tandem transformation was also possible via chemoselective [Cp*Ru]-catalyzed hydrogenation of the resulting homodienes.

Graphical abstract: [Cp*Ru]-catalyzed selective coupling/hydrogenation

Supplementary files

Article information

Article type
Paper
Submitted
06 Oct 2014
Accepted
03 Dec 2014
First published
03 Dec 2014

Catal. Sci. Technol., 2015,5, 1650-1657

[Cp*Ru]-catalyzed selective coupling/hydrogenation

I. Labed, A. Labed, Y. Sun, F. Jiang, M. Achard, S. Dérien, Z. Kabouche and C. Bruneau, Catal. Sci. Technol., 2015, 5, 1650 DOI: 10.1039/C4CY01303D

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