Issue 9, 2016
From the journal:

Chemical Communications

Metal-free oxidative cross-coupling of diazirines with arylboronic acids†

Guojiao Wu,a   Xia Zhao,*ab   Wenzhi Ji,a   Yan Zhanga  and  Jianbo Wang*a  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: wangjb@pku.edu.cn

b College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, China
E-mail: hxxyzhx@mail.tjnu.edu.cn

Abstract

We report herein a metal-free cross-coupling of diazirines with arylboronic acids under oxidative conditions. The reaction affords a series of substituted olefins. It is proposed that the interaction between the nitrogen on diazirine with arylboronic acid plays a key role in this transformation.

Graphical abstract: Metal-free oxidative cross-coupling of diazirines with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/C5CC08855K
Article type
Communication
Submitted
25 Oct 2015
Accepted
02 Dec 2015
First published
02 Dec 2015

Chem. Commun., 2016,52, 1961-1963

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Metal-free oxidative cross-coupling of diazirines with arylboronic acids

G. Wu, X. Zhao, W. Ji, Y. Zhang and J. Wang, Chem. Commun., 2016, 52, 1961 DOI: 10.1039/C5CC08855K

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