Issue 95, 2015
From the journal:

Chemical Communications

Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies†‡

Laura Ortega-Moreno,a   Riccardo Peloso,a   Celia Maya,a   Andrés Suáreza  and  Ernesto Carmona*a  

* Corresponding authors

a Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Sevilla and Consejo Superior de Investigaciones Científicas (CSIC), Avenida Américo Vespucio, 49, 41092 Sevilla, Spain
E-mail: guzman@us.es

Abstract

A novel terphenylphosphine PMe2ArDipp2 (1) (Dipp = 2,6-iPr2C6H3) forms stable Pt(0) complexes with ethene and 3,3-dimethylbut-1-ene that behave as sources of the reactive Pt(PMe2ArDipp2) fragment. The complexes are efficient catalysts for the selective hydrosilylation of terminal alkynes.

Graphical abstract: Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

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Article information

DOI
https://doi.org/10.1039/C5CC07308A
Article type
Communication
Submitted
03 Sep 2015
Accepted
25 Sep 2015
First published
28 Sep 2015

Chem. Commun., 2015,51, 17008-17011

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Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

L. Ortega-Moreno, R. Peloso, C. Maya, A. Suárez and E. Carmona, Chem. Commun., 2015, 51, 17008 DOI: 10.1039/C5CC07308A

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