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Issue 100, 2015
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Fluorine-controlled C–H borylation of arenes catalyzed by a PSiN-pincer platinum complex

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Abstract

An efficient, regioselective synthesis of fluorine-substituted arylboronic esters was achieved through fluorine-controlled C–H borylation of arenes with diboron catalyzed by a PSiN–platinum complex. The promising utility of the PSiN–platinum catalyst and its unique regioselectivity were demonstrated for the first time, which would complement the well-developed Ir-catalyzed C–H borylation.

Graphical abstract: Fluorine-controlled C–H borylation of arenes catalyzed by a PSiN-pincer platinum complex

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Publication details

The article was received on 29 Aug 2015, accepted on 21 Sep 2015 and first published on 21 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC07263H
Citation: Chem. Commun., 2015,51, 17662-17665
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    Fluorine-controlled C–H borylation of arenes catalyzed by a PSiN-pincer platinum complex

    J. Takaya, S. Ito, H. Nomoto, N. Saito, N. Kirai and N. Iwasawa, Chem. Commun., 2015, 51, 17662
    DOI: 10.1039/C5CC07263H

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