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Issue 91, 2015
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Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

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Abstract

Phenyl rings in phenyl- or phenyl-alkylphosphines are selectively deuterated at the ortho position using Ru/PVP nanoparticles, while are fully reduced in the case of arylphosphine oxide derivatives and do not react in the case of arylphosphite. This different behavior provides information about the coordination mode of each ligand.

Graphical abstract: Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

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Publication details

The article was received on 19 Aug 2015, accepted on 11 Sep 2015 and first published on 11 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC06984J
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 16342-16345
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    Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

    E. Bresó-Femenia, C. Godard, C. Claver, B. Chaudret and S. Castillón, Chem. Commun., 2015, 51, 16342
    DOI: 10.1039/C5CC06984J

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