Issue 87, 2015
From the journal:

Chemical Communications

Unprecedented side reactions in Stille coupling: desired ones for Stille polycondensation†

Hongyan Huang,ab   Guanyuan Jiao,ab   Shuli Liu,ab   Quan Li,ab   Xin Shi,ab   Nina Fu,ab   Lianhui Wang,*ab   Baomin Zhao*ab  and  Wei Huang*ac  

* Corresponding authors

a Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China

b National Jiangsu Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China
E-mail: iambmzhao@njupt.edu.cn
Fax: +86 6779 1691

c Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), National Jiangsu Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China
E-mail: iamwhuang@njtech.edu.cn
Fax: +34 952 132000

Abstract

Two types of unprecedented side reactions were identified in the Stille coupling reaction, including the direct C–H stannylation of the α-hydrogen of thiophene and the stannylation of arylbromides with trialkylstannane bromide. These results reveal the major source of enhancements for Stille polycondensation efficiency.

Graphical abstract: Unprecedented side reactions in Stille coupling: desired ones for Stille polycondensation

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Article information

DOI
https://doi.org/10.1039/C5CC05404D
Article type
Communication
Submitted
01 Jul 2015
Accepted
01 Sep 2015
First published
02 Sep 2015

Chem. Commun., 2015,51, 15846-15849

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Unprecedented side reactions in Stille coupling: desired ones for Stille polycondensation

H. Huang, G. Jiao, S. Liu, Q. Li, X. Shi, N. Fu, L. Wang, B. Zhao and W. Huang, Chem. Commun., 2015, 51, 15846 DOI: 10.1039/C5CC05404D

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