Issue 63, 2015
From the journal:

Chemical Communications

A 1,2,4-diazaphospholyl radical and its nitrogen–phosphorus coupled dimer: synthesis, X-ray structural characterization, EPR analysis, and computational studies†

Jing Su,a   Bingqiang Wang,a   Dongling Liu,a   Libo Du,b   Yang Liu,b   Jihu Suc  and  Wenjun Zheng*ad  

* Corresponding authors

a Institute of Organic Chemistry & College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province, China
E-mail: wjzheng@sxnu.edu.cn

b Beijing Institute of Chemistry, Chinese Academy of Science, Zhongguancun North First Street 2, Beijing 100190, China

c Department of Modern Physics, University of Science and Technology of China, Hefei 230026, China

d Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Gongyuan Street 1, Linfen, Shanxi Province, China

Abstract

The oxidation of 1,2,4-diazaphospholide potassium (K+[2−]) produces a neutral 1,2,4-diazaphospholyl radical (2˙) which can subsequently afford the 2(N)–2(P) dimer involving a N–P linkage.

Graphical abstract: A 1,2,4-diazaphospholyl radical and its nitrogen–phosphorus coupled dimer: synthesis, X-ray structural characterization, EPR analysis, and computational studies

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Article information

DOI
https://doi.org/10.1039/C5CC05125H
Article type
Communication
Submitted
22 Jun 2015
Accepted
30 Jun 2015
First published
30 Jun 2015

Chem. Commun., 2015,51, 12680-12683

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A 1,2,4-diazaphospholyl radical and its nitrogen–phosphorus coupled dimer: synthesis, X-ray structural characterization, EPR analysis, and computational studies

J. Su, B. Wang, D. Liu, L. Du, Y. Liu, J. Su and W. Zheng, Chem. Commun., 2015, 51, 12680 DOI: 10.1039/C5CC05125H

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