Issue 68, 2015
From the journal:

Chemical Communications

Palladium-catalyzed cross-coupling of aryl fluorides with N-tosylhydrazones via C–F bond activation†

Haiqing Luo,ab   Guojiao Wu,b   Shuai Xu,b   Kang Wang,b   Chaoqiang Wu,b   Yan Zhangb  and  Jianbo Wang*b  

* Corresponding authors

a Department of Chemistry & Chemical Engineering, Gannan Normal University, Ganzhou 341000, China

b Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: wangjb@pku.edu.cn

Abstract

A palladium-catalyzed cross-coupling reaction of electron-deficient aryl fluorides with aryl N-tosylhydrazones has been reported. Mechanistically, this approach involves C–F bond activation and migratory insertion of palladium carbene as the two key steps.

Graphical abstract: Palladium-catalyzed cross-coupling of aryl fluorides with N-tosylhydrazones via C–F bond activation

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Article information

DOI
https://doi.org/10.1039/C5CC05035A
Article type
Communication
Submitted
18 Jun 2015
Accepted
14 Jul 2015
First published
15 Jul 2015

Chem. Commun., 2015,51, 13321-13323

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Palladium-catalyzed cross-coupling of aryl fluorides with N-tosylhydrazones via C–F bond activation

H. Luo, G. Wu, S. Xu, K. Wang, C. Wu, Y. Zhang and J. Wang, Chem. Commun., 2015, 51, 13321 DOI: 10.1039/C5CC05035A

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