Issue 69, 2015
From the journal:

Chemical Communications

An ultra-microporous organic polymer for high performance carbon dioxide capture and separation†

Ali Kemal Sekizkardes,*a   Jeffrey T. Culp,ab   Timur Islamoglu,c   Anne Marti,a   David Hopkinson,a   Christina Myers,a   Hani M. El-Kaderic  and  Hunaid B. Nulwala ORCID logo ad  

* Corresponding authors

a U.S. Department of Energy National Energy and Technology Laboratory, Pittsburgh, Pennsylvania 15236, USA
E-mail: ali.sekizkardes@netl.doe.gov
Tel: +1 (412) 386-7255

b AECOM PO Box 618, South Park, PA 15219, USA

c Department of Chemistry, Virginia Commonwealth University, 1001 W. Main St., Richmond, VA 23284-2006, USA

d Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, USA

Abstract

Rational design concepts were used to prepare a novel porous benzimidazole-linked polymer (BILP-101) in a simple one-pot reaction. BILP-101 has exhibited ultra-microporosity (0.54 nm), very high CO2 uptake (∼1 mmol g−1, 4 wt%, 0.15 bar/298 K) and exceptional CO2/N2 selectivity of 80 (298 K), which results in remarkable working capacity and regenerability for CO2 capture applications.

Graphical abstract: An ultra-microporous organic polymer for high performance carbon dioxide capture and separation

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Article information

DOI
https://doi.org/10.1039/C5CC04656D
Article type
Communication
Submitted
05 Jun 2015
Accepted
15 Jul 2015
First published
15 Jul 2015

Chem. Commun., 2015,51, 13393-13396

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An ultra-microporous organic polymer for high performance carbon dioxide capture and separation

A. K. Sekizkardes, J. T. Culp, T. Islamoglu, A. Marti, D. Hopkinson, C. Myers, H. M. El-Kaderi and H. B. Nulwala, Chem. Commun., 2015, 51, 13393 DOI: 10.1039/C5CC04656D

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