Issue 61, 2015
From the journal:

Chemical Communications

Programmed assembly of 4,2′:6′,4′′-terpyridine derivatives into porous, on-surface networks†

Thomas Nijs,a   Frederik J. Malzner,b   Shadi Fatayer,ac   Aneliia Wäckerlin,a   Sylwia Nowakowska,a   Edwin C. Constable,b   Catherine E. Housecroft*b  and  Thomas A. Jung*d  

* Corresponding authors

a Department of Physics, University of Basel, Klingelbergstrasse 82, 4056 Basel, Switzerland

b Department of Chemistry, University of Basel, Spitalstrasse 51, 4056 Basel, Switzerland
E-mail: catherine.housecroft@unibas.ch

c Instituto de Física “Gleb Wataghin”, Universidade Estadual de Campinas, Rua Sérgio Buarque de Holanda 777, 13083-859 Campinas, SP, Brazil

d Laboratory for Micro- and Nanotechnology, Paul Scherrer Institut, 5232 Villigen, Switzerland
E-mail: thomas.jung@psi.ch

Abstract

The use of divergent, V-shaped, 4,2′:6′,4′′-terpyridine building blocks that self-assemble into hydrogen-bonded domains and upon addition of copper atoms undergo metallation with concomitant transformation into a coordination network is described; multiple energetically similar structural motifs are observed in both hydrogen-bonded and adatom-coordinated networks.

Graphical abstract: Programmed assembly of 4,2′:6′,4′′-terpyridine derivatives into porous, on-surface networks

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Article information

DOI
https://doi.org/10.1039/C5CC04186D
Article type
Communication
Submitted
21 May 2015
Accepted
23 Jun 2015
First published
03 Jul 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 12297-12300

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Programmed assembly of 4,2′:6′,4′′-terpyridine derivatives into porous, on-surface networks

T. Nijs, F. J. Malzner, S. Fatayer, A. Wäckerlin, S. Nowakowska, E. C. Constable, C. E. Housecroft and T. A. Jung, Chem. Commun., 2015, 51, 12297 DOI: 10.1039/C5CC04186D

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