Abstract
Thiol (–SH) groups within a Zr(IV)-based metal–organic framework (MOF) anchor Hg(II) atoms; oxidation by H2O2 then leads to acidic sulfonate functions for catalyzing acetylene hydration at room temperature.
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* Corresponding authors
a
Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, China
E-mail:
zhengtao@cityu.edu.hk
b Department of Physics, University of Massachusetts, Amherst, Massachusetts 01003, USA
c School of Chemical Engineering and Light Industry, University of Technology, Guangzhou 510006, Guangdong, China
Thiol (–SH) groups within a Zr(IV)-based metal–organic framework (MOF) anchor Hg(II) atoms; oxidation by H2O2 then leads to acidic sulfonate functions for catalyzing acetylene hydration at room temperature.
K. Yee, Y. Wong, M. Zha, R. Y. Adhikari, M. T. Tuominen, J. He and Z. Xu, Chem. Commun., 2015, 51, 10941 DOI: 10.1039/C5CC03943F
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