Issue 64, 2015
From the journal:

Chemical Communications

A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide†

Jung-Ho Son*a  and  William H. Caseyab  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Ave. Davis, CA 95616, USA
E-mail: junghoson@gmail.com

b Department of Chemistry, Department of Earth and Planetary Sciences, University of California, Davis, One Shields Ave. Davis, CA 95616, USA

Abstract

Polyoxoniobate clusters that are stable in acidic solutions are rare and particularly useful in industrial processes. Here we report a new pentaphosphate niobate polyoxometalate cluster (TMA)9H3Nb9P5O41·28H2O (Nb9P5) that is stable over a wide pH range and that can be converted reversibly into the peroxo form.

Graphical abstract: A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/C5CC03782D
Article type
Communication
Submitted
06 May 2015
Accepted
24 Jun 2015
First published
25 Jun 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 12744-12747

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A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide

J. Son and W. H. Casey, Chem. Commun., 2015, 51, 12744 DOI: 10.1039/C5CC03782D

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