An efficient Rh(III)-catalyzed 7-azaindole synthesis was developed via C–H activation/annulative coupling of aminopyridines with alkynes. The reaction was highly regioselective and tolerated various functional groups, permitting the construction of various 7-azaindoles.
Y. Kim and S. Hong, Chem. Commun., 2015, 51, 11202 DOI: 10.1039/C5CC03497C
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