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Issue 59, 2015
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Catalytic chemoselective [3+3] cycloadditions of azomethine ylides with quinone monoimides leading to the construction of a dihydrobenzoxazine scaffold

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Abstract

A chemoselective [3+3] cycloaddition of in situ generated azomethine ylides with quinone monoimides has been established, which efficiently led to the construction of dihydrobenzoxazine frameworks with biological relevance, with excellent chemoselectivities and high yields (up to >95 : 5 cr and 98% yield).

Graphical abstract: Catalytic chemoselective [3+3] cycloadditions of azomethine ylides with quinone monoimides leading to the construction of a dihydrobenzoxazine scaffold

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Publication details

The article was received on 22 Apr 2015, accepted on 10 Jun 2015 and first published on 10 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC03341A
Citation: Chem. Commun., 2015,51, 11798-11801
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    Catalytic chemoselective [3+3] cycloadditions of azomethine ylides with quinone monoimides leading to the construction of a dihydrobenzoxazine scaffold

    C. Wang, R. Zhu, Y. Zhang and F. Shi, Chem. Commun., 2015, 51, 11798
    DOI: 10.1039/C5CC03341A

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