Cp*Rh(III) and Cp*Ir(III)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

Shang-Shi Zhang; Chun-Yong Jiang; Jia-Qiang Wu; Xu-Ge Liu; Qingjiang Li; Zhi-Shu Huang; Ding Li; Honggen Wang

doi:10.1039/C5CC03187G

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CpRh(iii) and CpIr(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols†

Shang-Shi Zhang,‡^a Chun-Yong Jiang,‡^a Jia-Qiang Wu,^a Xu-Ge Liu,^a Qingjiang Li,^a Zhi-Shu Huang,^a Ding Li*^a and Honggen Wang*^a

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* Corresponding authors

^a School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou 510006, China
E-mail: wanghg3@mail.sysu.edu.cn, liding@mail.sysu.edu.cn

Abstract

Cp*Rh(III)- and Cp*Ir(III)-catalysed direct C–H arylation with quinone diazides as efficient coupling partners is disclosed. This redox-neutral protocol offers a facile, operationally simple and environmentally benign access to arylated phenols. The reaction represents the first example of Cp*Ir(III)-catalysed C–H direct arylation reaction.

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Article information

DOI: https://doi.org/10.1039/C5CC03187G
Article type: Communication
Submitted: 17 Apr 2015
Accepted: 14 May 2015
First published: 14 May 2015

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Chem. Commun., 2015,51, 10240-10243

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CpRh(III) and CpIr(III)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

S. Zhang, C. Jiang, J. Wu, X. Liu, Q. Li, Z. Huang, D. Li and H. Wang, Chem. Commun., 2015, 51, 10240 DOI: 10.1039/C5CC03187G

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