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Issue 37, 2015
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Nickel-catalyzed directed sulfenylation of sp2 and sp3 C–H bonds

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Abstract

Directed sulfenylation of both sp2 and sp3 C–H bonds was achieved through nickel catalyzed directed C–S bond formation, giving the desired product in good to excellent yield (up to 90%). Other metal cations, including Cu, Fe, Pd, Rh, Ru and Co, gave almost no reaction under identical conditions, which highlighted the unique reactivity of this Ni system.

Graphical abstract: Nickel-catalyzed directed sulfenylation of sp2 and sp3 C–H bonds

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Publication details

The article was received on 09 Mar 2015, accepted on 27 Mar 2015 and first published on 30 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC01970B
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 7863-7866
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    Nickel-catalyzed directed sulfenylation of sp2 and sp3 C–H bonds

    X. Ye, J. L. Petersen and X. Shi, Chem. Commun., 2015, 51, 7863
    DOI: 10.1039/C5CC01970B

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