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Issue 44, 2015
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Exploiting amphiphilicity: facile metal free access to thianthrenes and related sulphur heterocycles

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Abstract

Benzodithioloimines are reacted with arynes or alkynes substituted with electron-withdrawing groups to afford the corresponding thianthrene or benzo[b][1,4]dithiine derivatives. The transformation takes place under mild reaction conditions without any transition metal. Furthermore, the reaction mode could be expanded to 2-thiocyanatopyrroles yielding pyrrolothiazoles.

Graphical abstract: Exploiting amphiphilicity: facile metal free access to thianthrenes and related sulphur heterocycles

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Publication details

The article was received on 28 Feb 2015, accepted on 28 Apr 2015 and first published on 28 Apr 2015


Article type: Communication
DOI: 10.1039/C5CC01757B
Citation: Chem. Commun., 2015,51, 9165-9168
  • Open access: Creative Commons BY license
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    Exploiting amphiphilicity: facile metal free access to thianthrenes and related sulphur heterocycles

    M. Pawliczek, L. K. B. Garve and D. B. Werz, Chem. Commun., 2015, 51, 9165
    DOI: 10.1039/C5CC01757B

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