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Issue 32, 2015
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Copper-catalyzed oxygen atom transfer of N-oxides leading to a facile deoxygenation procedure applicable to both heterocyclic and amine N-oxides

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Abstract

Deoxygenation of various types of N-oxides including both heterocyclic and alkyl(aryl)amine derivatives has successfully been developed by the copper-catalyzed oxygen atom transfer using diazo compounds as the oxygen acceptor. The reaction proceeds smoothly over a broad range of substrates with excellent functional group tolerance under mild conditions.

Graphical abstract: Copper-catalyzed oxygen atom transfer of N-oxides leading to a facile deoxygenation procedure applicable to both heterocyclic and amine N-oxides

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Publication details

The article was received on 27 Feb 2015, accepted on 18 Mar 2015 and first published on 19 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC01739D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 7035-7038
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    Copper-catalyzed oxygen atom transfer of N-oxides leading to a facile deoxygenation procedure applicable to both heterocyclic and amine N-oxides

    J. Jeong, D. Lee and S. Chang, Chem. Commun., 2015, 51, 7035
    DOI: 10.1039/C5CC01739D

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