Issue 36, 2015
From the journal:

Chemical Communications

Dioxygen activation and two consecutive oxidative decarboxylations of phenylpyruvate by nonheme iron(ii) complexes: functional models of hydroxymandelate synthase (HMS) and CloR†

Debobrata Sheet,a   Shrabanti Bhattacharyaa  and  Tapan Kanti Paine*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A&2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032, India
E-mail: ictkp@iacs.res.in
Fax: +91-33-2473-2805
Tel: +91-33-2473-4971

Abstract

Two mononuclear iron(II)–phenylpyruvate complexes of monoanionic facial N3 ligands are reported to react with dioxygen to undergo two consecutive oxidative decarboxylation steps via an iron–mandelate complex mimicking the function of HMS and CloR.

Graphical abstract: Dioxygen activation and two consecutive oxidative decarboxylations of phenylpyruvate by nonheme iron(ii) complexes: functional models of hydroxymandelate synthase (HMS) and CloR

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC01652E
Article type
Communication
Submitted
24 Feb 2015
Accepted
27 Mar 2015
First published
27 Mar 2015

Chem. Commun., 2015,51, 7681-7684

Author version available

Download author version (PDF)

Permissions

Request permissions

Dioxygen activation and two consecutive oxidative decarboxylations of phenylpyruvate by nonheme iron(II) complexes: functional models of hydroxymandelate synthase (HMS) and CloR

D. Sheet, S. Bhattacharya and T. K. Paine, Chem. Commun., 2015, 51, 7681 DOI: 10.1039/C5CC01652E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements