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Issue 31, 2015
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Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

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Abstract

Herein, we report simple flow reactor designs that enable photo-controlled living radical polymerization (photo-CRP) from trithiocarbonates (TTCs) with significant enhancements in scalability and reaction rates compared to the analogous batch reactions. We also demonstrate the “on/off” photo-switchability of this reaction under flow conditions.

Graphical abstract: Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

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Publication details

The article was received on 20 Feb 2015, accepted on 17 Mar 2015 and first published on 17 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC01562F
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 6742-6745
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    Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

    M. Chen and J. A. Johnson, Chem. Commun., 2015, 51, 6742
    DOI: 10.1039/C5CC01562F

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