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Issue 39, 2015
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Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

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Abstract

2,2-Dimethyl-1,3-dioxolane connected to two pyrene moieties through flexible wires in chloroform exhibited cryptochirality in the ground state, as proven by the lack of detectable circular dichroism signals. This cryptochirality was deciphered in the photoexcited state by circularly polarised luminescence signals.

Graphical abstract: Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

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Publication details

The article was received on 17 Feb 2015, accepted on 20 Mar 2015 and first published on 20 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC01465D
Citation: Chem. Commun., 2015,51, 8237-8240
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    Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

    T. Amako, K. Nakabayashi, N. Suzuki, S. Guo, N. A. A. Rahim, T. Harada, M. Fujiki and Y. Imai, Chem. Commun., 2015, 51, 8237
    DOI: 10.1039/C5CC01465D

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