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Issue 40, 2015
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Linearly bridging CO2 in a metal–organic framework

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Abstract

A very rare structurally characterized CO2-coordinated metal–organic framework was synthesized by a solvothermal reaction. The CO2 ligand links two open Zn metal centers in a linear and symmetrical μ(O,O′) coordination mode with a C[double bond, length as m-dash]O distance of 1.107(4) Å. The new complex reported here is stable under ambient conditions and may provide a new strategy for CO2 fixation.

Graphical abstract: Linearly bridging CO2 in a metal–organic framework

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Publication details

The article was received on 10 Feb 2015, accepted on 25 Feb 2015 and first published on 25 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC01244A
Citation: Chem. Commun., 2015,51, 8446-8449
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    Linearly bridging CO2 in a metal–organic framework

    F. Yi, H. Jiang and Z. Sun, Chem. Commun., 2015, 51, 8446
    DOI: 10.1039/C5CC01244A

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