Issue 38, 2015
From the journal:

Chemical Communications

Ammonia detection by using flexible Lewis acidic sites in luminescent porous frameworks constructed from a bipyridinium derivative†

Cheng Chen,a   Li-Xuan Cai,a   Bin Tan,a   Ya-Jun Zhang,a   Xiao-Dong Yanga  and  Jie Zhang*ab  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, Fujian 350002, P. R. China
E-mail: zhangjie@fjirsm.ac.cn

b School of Chemistry, Beijing Institute of Technology, Beijing, P. R. China

Abstract

A flexible bipyridinium ligand with Lewis acidic sites has been introduced into two isomorphous metal–organic frameworks to yield luminescent porous materials with subtriangular pore windows, which exhibit sensitive fluorescent response for ammonia molecules and can be proved at the molecular level by Raman spectroscopy.

Graphical abstract: Ammonia detection by using flexible Lewis acidic sites in luminescent porous frameworks constructed from a bipyridinium derivative

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Article information

DOI
https://doi.org/10.1039/C5CC01239B
Article type
Communication
Submitted
10 Feb 2015
Accepted
27 Mar 2015
First published
27 Mar 2015

Chem. Commun., 2015,51, 8189-8192

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Ammonia detection by using flexible Lewis acidic sites in luminescent porous frameworks constructed from a bipyridinium derivative

C. Chen, L. Cai, B. Tan, Y. Zhang, X. Yang and J. Zhang, Chem. Commun., 2015, 51, 8189 DOI: 10.1039/C5CC01239B

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