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Issue 25, 2015
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Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation

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Abstract

Two tetrahydocarbazolone derivatives were found to show multiple unsolvated crystal forms. A persistent dimer motif was detected in solution by FTIR spectroscopy that is maintained in the kinetic crystal forms. Rationally introduced steric bulk induces the formation of a more stable catemeric form.

Graphical abstract: Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation

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Publication details

The article was received on 31 Dec 2014, accepted on 10 Feb 2015 and first published on 17 Feb 2015


Article type: Communication
DOI: 10.1039/C4CC10453F
Citation: Chem. Commun., 2015,51, 5314-5317
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    Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation

    R. M. Edkins, E. Hayden, J. W. Steed and K. Fucke, Chem. Commun., 2015, 51, 5314
    DOI: 10.1039/C4CC10453F

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