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The synthesis of novel, chignolin-derived peptides comprising the azobenzene photoswitch [3-(3-aminomethyl)phenylazo]phenylacetic acid (AMPP) is reported. Reversible photoswitching behavior led to folding into β-hairpin-like structures, as unequivocally demonstrated by CD, FT-IR and NMR spectroscopy.
T. Podewin, M. S. Rampp, I. Turkanovic, K. L. Karaghiosoff, W. Zinth and A. Hoffmann-Röder, Chem. Commun., 2015, 51, 4001 DOI: 10.1039/C4CC10304A
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