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Issue 17, 2015
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An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

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Abstract

We present the first example of an extended 3D framework synthesised without the use of an isolable organic component. This is achieved by the combination of two cage complexes isolated and functionalised prior to synthesis; [nPr2NH2][Cr7NiF8(O2CtBu)14(O2CC5H4N)2] and [Fe2CoO(O2CtBu)6(HO2CtBu)3], where the former is as a bidentate linker, bridging between three nodes of the latter.

Graphical abstract: An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

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Publication details

The article was received on 16 Dec 2014, accepted on 22 Jan 2015 and first published on 03 Feb 2015


Article type: Communication
DOI: 10.1039/C4CC10035B
Citation: Chem. Commun., 2015,51, 3533-3536
  • Open access: Creative Commons BY license
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    An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

    G. F. S. Whitehead, S. J. Teat, K. J. Gagnon, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2015, 51, 3533
    DOI: 10.1039/C4CC10035B

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