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Issue 19, 2015
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A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors

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Abstract

We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid–base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.

Graphical abstract: A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors

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Publication details

The article was received on 11 Dec 2014, accepted on 22 Jan 2015 and first published on 23 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC09917F
Citation: Chem. Commun., 2015,51, 4032-4035
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    A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors

    D. Prochowicz, K. Sokołowski, I. Justyniak, A. Kornowicz, D. Fairen-Jimenez, T. Friščić and J. Lewiński, Chem. Commun., 2015, 51, 4032
    DOI: 10.1039/C4CC09917F

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