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Issue 16, 2015
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Modification of 1,2,4,5-tetrazine with cationic rhenium(I) polypyridine units to afford phosphorogenic bioorthogonal probes with enhanced reaction kinetics

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Abstract

New phosphorogenic bioorthogonal probes derived from mononuclear and binuclear rhenium(I) polypyridine complexes containing a 1,2,4,5-tetrazine moiety were designed; these complexes displayed substantial dienophile-induced emission enhancement, and accelerated reaction kinetics and could target a protein conjugate in living cells.

Graphical abstract: Modification of 1,2,4,5-tetrazine with cationic rhenium(i) polypyridine units to afford phosphorogenic bioorthogonal probes with enhanced reaction kinetics

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Publication details

The article was received on 29 Nov 2014, accepted on 18 Jan 2015 and first published on 21 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC09532D
Citation: Chem. Commun., 2015,51, 3442-3445
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    Modification of 1,2,4,5-tetrazine with cationic rhenium(I) polypyridine units to afford phosphorogenic bioorthogonal probes with enhanced reaction kinetics

    A. W. Choi, K. K. Tso, V. M. Yim, H. Liu and K. K. Lo, Chem. Commun., 2015, 51, 3442
    DOI: 10.1039/C4CC09532D

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