Issue 25, 2015
From the journal:

Chemical Communications

C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation†

Jyh-Herng Ruei,a   Patteti Venukumar,a   Arun B. Inglea  and  Kwok-Kong Tony Mong*a  

* Corresponding authors

a Applied Chemistry Department, National Chiao Tung University (NCTU), 1001 Ta Hsueh Road, Taiwan
E-mail: tmong@mail.nctu.edu.tw
Fax: +886-3-5131204

Abstract

We reported a remote control glycosylation method using the picoloyl protecting group for 2-deoxy-β-glycosidic bond formation. The method is applicable to various 2-deoxythioglycosyl donors and the utility is illustrated by the synthesis of a deoxytrisaccharide component of landomycins.

Graphical abstract: C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

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Article information

DOI
https://doi.org/10.1039/C4CC08465A
Article type
Communication
Submitted
27 Oct 2014
Accepted
27 Nov 2014
First published
27 Nov 2014

Chem. Commun., 2015,51, 5394-5397

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C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

J. Ruei, P. Venukumar, A. B. Ingle and K. T. Mong, Chem. Commun., 2015, 51, 5394 DOI: 10.1039/C4CC08465A

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