Issue 7, 2015

Single-shot titrations and reaction monitoring by slice-selective NMR spectroscopy

Abstract

A new method, based on slice-selective NMR spectroscopy of inhomogeneous mixtures, is introduced to perform NMR titrations and reaction monitoring in a single experiment. The method was applied to the titration of a lithium salt with 12-crown-4, and to the reaction of nBuLi with N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDTA).

Graphical abstract: Single-shot titrations and reaction monitoring by slice-selective NMR spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
21 Oct 2014
Accepted
28 Nov 2014
First published
28 Nov 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 1275-1277

Author version available

Single-shot titrations and reaction monitoring by slice-selective NMR spectroscopy

T. Niklas, D. Stalke and M. John, Chem. Commun., 2015, 51, 1275 DOI: 10.1039/C4CC08329F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements