A Tröger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid†
Abstract
A Tröger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(III) complex. The resultant TB-MOP–Ru showed good CO2 and H2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number up to 2254 at 40 °C.