Self-assembled resorcin[4]arene hexamer catalyzes the intramolecular hydroalkoxylation of unsaturated alcohols to the corresponding cyclic ethers under mild conditions. The mode of catalysis and encapsulation-based substrate selectivity of the host efficiently mimic the basic principle of operation observed in enzymes.
L. Catti and K. Tiefenbacher, Chem. Commun., 2015, 51, 892 DOI: 10.1039/C4CC08211G
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