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Issue 4, 2015
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Pd(II)-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimine esters and a DFT study of its mechanism

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Abstract

A palladium-catalyzed asymmetric arylation of cyclic N-sulfonyl ketimine esters is described. The desired products could be prepared with excellent yields (up to 99%) and enantioselectivities (up to 99% ee) under mild reaction conditions. Furthermore, a possible reaction mechanism was determined using DFT calculations.

Graphical abstract: Pd(ii)-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimine esters and a DFT study of its mechanism

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The article was received on 23 Dec 2014, accepted on 09 Feb 2015 and first published on 11 Feb 2015


Article type: Research Article
DOI: 10.1039/C4QO00347K
Citation: Org. Chem. Front., 2015,2, 398-402
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    Pd(II)-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimine esters and a DFT study of its mechanism

    M. Quan, G. Yang, F. Xie, I. D. Gridnev and W. Zhang, Org. Chem. Front., 2015, 2, 398
    DOI: 10.1039/C4QO00347K

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