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Issue 18, 2015
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Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex

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Abstract

We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers.

Graphical abstract: Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex

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Publication details

The article was received on 07 Nov 2014, accepted on 20 Jan 2015 and first published on 04 Feb 2015


Article type: Communication
DOI: 10.1039/C4CC08920K
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2015,51, 3832-3834
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    Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex

    B. J. Groombridge, S. M. Goldup and I. Larrosa, Chem. Commun., 2015, 51, 3832
    DOI: 10.1039/C4CC08920K

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