Issue 34, 2014
From the journal:

Journal of Materials Chemistry A

Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture†

Jingzhi Lua  and  Jian Zhang*a  

* Corresponding authors

a Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588, USA
E-mail: jzhang3@unl.edu

Abstract

A facile Zn-induced reductive homocoupling reaction was used to synthesize azo-linked porous organic frameworks (azo-POFs) from easily accessed nitro monomers. Azo-POF-2 exhibits the highest CO2/N2 selectivity of 76 at 273 K among all self-coupled azo-linked porous polymers.

Graphical abstract: Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

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Article information

DOI
https://doi.org/10.1039/C4TA03015J
Article type
Communication
Submitted
14 Jun 2014
Accepted
26 Jun 2014
First published
02 Jul 2014

J. Mater. Chem. A, 2014,2, 13831-13834

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Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

J. Lu and J. Zhang, J. Mater. Chem. A, 2014, 2, 13831 DOI: 10.1039/C4TA03015J

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