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Issue 34, 2014
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Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

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Abstract

A facile Zn-induced reductive homocoupling reaction was used to synthesize azo-linked porous organic frameworks (azo-POFs) from easily accessed nitro monomers. Azo-POF-2 exhibits the highest CO2/N2 selectivity of 76 at 273 K among all self-coupled azo-linked porous polymers.

Graphical abstract: Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

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Publication details

The article was received on 14 Jun 2014, accepted on 26 Jun 2014 and first published on 02 Jul 2014


Article type: Communication
DOI: 10.1039/C4TA03015J
Author version available: Download Author version (PDF)
Citation: J. Mater. Chem. A, 2014,2, 13831-13834
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    Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

    J. Lu and J. Zhang, J. Mater. Chem. A, 2014, 2, 13831
    DOI: 10.1039/C4TA03015J

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