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Issue 41, 2014
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Effects of ultraviolet soaking on surface electronic structures of solution processed ZnO nanoparticle films in polymer solar cells

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Abstract

We systematically show the effect of UV-light soaking on surface electronic structures and chemical states of solution processed ZnO nanoparticle (ZnONP) films in UHV, dry air and UV–ozone. UV exposure in UHV induces a slight decrease in work function and surface-desorption of chemisorbed oxygen, whereas UV exposure in the presence of oxygen causes an increase in work function due to oxygen atom vacancy filling in the ZnO matrix. We demonstrate that UV-light soaking in combination with vacuum or oxygen can tune the work function of the ZnONP films over a range exceeding 1 eV. Based on photovoltaic performance and diode measurements, we conclude that the oxygen atom vacancy filling occurs mainly at the surface of the ZnONP films and that the films consequently retain their n-type behavior despite a significant increase in the measured work function.

Graphical abstract: Effects of ultraviolet soaking on surface electronic structures of solution processed ZnO nanoparticle films in polymer solar cells

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Publication details

The article was received on 29 May 2014, accepted on 02 Sep 2014 and first published on 03 Sep 2014


Article type: Paper
DOI: 10.1039/C4TA02695K
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Citation: J. Mater. Chem. A, 2014,2, 17676-17682
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    Effects of ultraviolet soaking on surface electronic structures of solution processed ZnO nanoparticle films in polymer solar cells

    Q. Bao, X. Liu, Y. Xia, F. Gao, L. Kauffmann, O. Margeat, J. Ackermann and M. Fahlman, J. Mater. Chem. A, 2014, 2, 17676
    DOI: 10.1039/C4TA02695K

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