Issue 107, 2014
From the journal:

RSC Advances

Highly luminescent imidoylamidinato platinum(ii) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents†

Tomohiro Tanaka,a   Rie Nouchi,a   Yoshihide Nakao,b   Yasuhiro Arikawaa  and  Keisuke Umakoshi*a  

* Corresponding authors

a Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, Bunkyo-machi, Nagasaki 852-8521, Japan
E-mail: kumks@nagasaki-u.ac.jp

b Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kyushu Sangyo University, Matsukadai, Higashi-ku, Fukuoka 813-8503, Japan

Abstract

A series of imidoylamidinato Pt(II) complexes have been prepared by the reaction of [Pt(bpy)(RCN)2]2+ (R = Me, Et, Ph) generated in a nitrile solution with 1H-pyrazole-1-carboxamidine. These complexes exhibit bright yellow or yellow-green luminescence in the solid state and mechanochromic behavior.

Graphical abstract: Highly luminescent imidoylamidinato platinum(ii) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents

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Article information

DOI
https://doi.org/10.1039/C4RA11744A
Article type
Communication
Submitted
03 Oct 2014
Accepted
11 Nov 2014
First published
18 Nov 2014

RSC Adv., 2014,4, 62186-62189

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Highly luminescent imidoylamidinato platinum(II) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents

T. Tanaka, R. Nouchi, Y. Nakao, Y. Arikawa and K. Umakoshi, RSC Adv., 2014, 4, 62186 DOI: 10.1039/C4RA11744A

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