We have developed an efficient and transition metal free methodology for the synthesis of 2,4,6-trisubstituted pyrimidines by the Cope-type hydroamination reaction of 1,4-diarylbuta-1,3-diynes with amidines in DMSO solvent.
R. Singha and J. K. Ray, RSC Adv., 2014, 4, 44052 DOI: 10.1039/C4RA07690G
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