Issue 90, 2014

Experimental and DFT study on the indium-mediated synthesis of benzophenones via arylstannanes

Abstract

Experimental results of the solvent-free, indium-promoted reaction of aroyl chlorides with arylstannanes showed a narrow scope; its efficiency depends both on the extent of methylation in the latter and on the nature, number and position of the substituents in the former. With the purpose of explaining experimental results, a theoretical analysis with DFT methods was performed for a set of selected cases.

Graphical abstract: Experimental and DFT study on the indium-mediated synthesis of benzophenones via arylstannanes

Supplementary files

Article information

Article type
Paper
Submitted
18 Jul 2014
Accepted
18 Sep 2014
First published
18 Sep 2014

RSC Adv., 2014,4, 49079-49085

Author version available

Experimental and DFT study on the indium-mediated synthesis of benzophenones via arylstannanes

M. J. Lo Fiego, V. B. Dorn, M. A. Badajoz, M. T. Lockhart and A. B. Chopa, RSC Adv., 2014, 4, 49079 DOI: 10.1039/C4RA07305C

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