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Issue 28, 2014
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One-step chemoselective conversion of tetrahydropyranyl ethers to silyl-protected alcohols

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Abstract

Aluminium trichloride catalyses the expeditious direct conversion of tetrahydropyranyl ethers to silyl ethers. This one-step transformation is chemoselective versus deprotection of the acetal and hydrosilylation of unsaturated carbon–carbon bonds, and can also be applied to linear acetals. A possible mechanism is tentatively proposed.

Graphical abstract: One-step chemoselective conversion of tetrahydropyranyl ethers to silyl-protected alcohols

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Publication details

The article was received on 22 Jan 2014, accepted on 12 Mar 2014 and first published on 12 Mar 2014


Article type: Paper
DOI: 10.1039/C4RA00655K
Author version available: Download Author version (PDF)
Citation: RSC Adv., 2014,4, 14475-14479
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    One-step chemoselective conversion of tetrahydropyranyl ethers to silyl-protected alcohols

    J. Bergueiro, J. Montenegro, C. Saá and S. López, RSC Adv., 2014, 4, 14475
    DOI: 10.1039/C4RA00655K

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