Total syntheses of rubiginone A2, C2, and fujianmycin A

Devendar G. Vanga; Krishna P. Kaliappan

doi:10.1039/C3RA47775D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Total syntheses of rubiginone A₂, C₂, and fujianmycin A†

Devendar G. Vanga^a and Krishna P. Kaliappan*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400 076, India
E-mail: kpk@chem.iitb.ac.in
Fax: +91 22-2572-3480
Tel: +91 22-2576-7177

Abstract

The total syntheses of rubiginone A₂, C₂ and fujianmycin A are described. The synthesis involves Diels–Alder/aromatization and photo chemical reactions as key steps to construct the tetracyclic frame of benz[a]anthraquinone skeleton. Sharpless epoxidation, a copper-catalyzed regioselective epoxide opening, and enyne metathesis reactions are utilized as the key steps for the synthesis of chiral vinylcyclohexene.

Download options Please wait...

Supplementary files

Supplementary information PDF (1854K)

Article information

DOI: https://doi.org/10.1039/C3RA47775D
Article type: Paper
Submitted: 16 Nov 2013
Accepted: 06 Jan 2014
First published: 14 Jan 2014

Download Citation

RSC Adv., 2014,4, 12716-12722

Permissions

Request permissions

Total syntheses of rubiginone A₂, C₂, and fujianmycin A

D. G. Vanga and K. P. Kaliappan, RSC Adv., 2014, 4, 12716 DOI: 10.1039/C3RA47775D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

RSC Advances