Issue 17, 2014
From the journal:

RSC Advances

Effect of sodium acetate in atom transfer radical addition of polyhaloalkanes to olefins†

Yoshinari Sawama,*a   Ryosuke Nakatani,a   Takahiro Imanishi,a   Yuta Fujiwara,a   Yasunari Monguchia  and  Hironao Sajiki*a  

* Corresponding authors

a Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan
E-mail: sawama@gifu-pu.ac.jp, sajiki@gifu-pu.ac.jp
Fax: +81-58-230-8109

Abstract

The atom transfer radical addition of polyhaloalkanes, such as bromotrichloromethane and polyfluoroalkyl iodine, to olefins smoothly proceeds in the presence of sodium acetate as an efficient auxiliary agent in dimethoxyethane. The present transition metal- and peroxide-free methodology is applicable to a broad scope of substrates.

Graphical abstract: Effect of sodium acetate in atom transfer radical addition of polyhaloalkanes to olefins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3RA47457G
Article type
Communication
Submitted
10 Dec 2013
Accepted
16 Jan 2014
First published
17 Jan 2014

RSC Adv., 2014,4, 8657-8660

Permissions

Request permissions

Effect of sodium acetate in atom transfer radical addition of polyhaloalkanes to olefins

Y. Sawama, R. Nakatani, T. Imanishi, Y. Fujiwara, Y. Monguchi and H. Sajiki, RSC Adv., 2014, 4, 8657 DOI: 10.1039/C3RA47457G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements