Issue 8, 2014

N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

Abstract

N-heterocyclic carbene-catalyzed oxidative esterification of various aliphatic aldehydes is reported. A commercially available bisquinone is used as an external oxidant and rubidium carbonate is best suited as base to run these processes. With the novel method various aliphatic esters are directly obtained in good to excellent yields from the corresponding aldehydes and alcohols.

Graphical abstract: N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

Supplementary files

Article information

Article type
Research Article
Submitted
03 Jun 2014
Accepted
21 Jul 2014
First published
22 Jul 2014

Org. Chem. Front., 2014,1, 936-939

Author version available

N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

R. C. Samanta and A. Studer, Org. Chem. Front., 2014, 1, 936 DOI: 10.1039/C4QO00164H

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