Issue 2, 2014
From the journal:

Organic Chemistry Frontiers

Aerobic oxidative C–B bond cleavage of arylboronic acids mediated by methylhydrazines†

Wei Ding,a   Jia-Rong Chen,*a   You-Quan Zou,a   Shu-Wen Duan,a   Liang-Qiu Lua  and  Wen-Jing Xiao*a  

* Corresponding authors

a CCNU–UOttawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
E-mail: chenjiarong@mail.ccnu.edu.cn, wxibao@mail.ccnu.edu.cn
Fax: +86 27 67862041
Tel: +86 27 67862041

Abstract

The aerobic oxidative C–B bond cleavage and ipso-hydroxylation of arylboronic acids mediated by methylhydrazine have been developed under metal-free conditions. This transformation affords structurally diverse phenols in good to excellent yields (26 examples, 71–99%).

Graphical abstract: Aerobic oxidative C–B bond cleavage of arylboronic acids mediated by methylhydrazines

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Article information

DOI
https://doi.org/10.1039/C3QO00026E
Article type
Research Article
Submitted
05 Nov 2013
Accepted
24 Dec 2013
First published
27 Jan 2014

Org. Chem. Front., 2014,1, 151-154

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Aerobic oxidative C–B bond cleavage of arylboronic acids mediated by methylhydrazines

W. Ding, J. Chen, Y. Zou, S. Duan, L. Lu and W. Xiao, Org. Chem. Front., 2014, 1, 151 DOI: 10.1039/C3QO00026E

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