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Issue 46, 2015
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Improved control through a semi-batch process in RAFT-mediated polymerization utilizing relatively poor leaving groups

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Abstract

The negative effect that a RAFT agent with a poor leaving group has on the evolution of molecular dispersity in a RAFT-mediated polymerization was shown to be mitigated by performing the polymerization in semi-batch mode. The result is attributed to an increase in the probability of transfer between the propagating radical and the leaving group during the polymerization. Also for RAFT-mediated polymerizations that use RAFT agents with efficient leaving groups, the evolution of molecular dispersity during a semi-batch polymerization improves compared to that for an analogous batch-mode reaction.

Graphical abstract: Improved control through a semi-batch process in RAFT-mediated polymerization utilizing relatively poor leaving groups

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Publication details

The article was received on 14 Aug 2015, accepted on 22 Sep 2015 and first published on 24 Sep 2015


Article type: Communication
DOI: 10.1039/C5PY01293G
Citation: Polym. Chem., 2015,6, 7945-7948
  • Open access: Creative Commons BY license
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    Improved control through a semi-batch process in RAFT-mediated polymerization utilizing relatively poor leaving groups

    A. Ilchev, R. Pfukwa, L. Hlalele, M. Smit and B. Klumperman, Polym. Chem., 2015, 6, 7945
    DOI: 10.1039/C5PY01293G

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