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Issue 24, 2016
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A mild preparation of alkynes from alkenyl triflates

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Abstract

We report herein a protocol for preparing alkynes from alkenyl triflates. Stoichiometric LiCl promotes this transformation in DMF at ambient temperature. A range of terminal and internal alkynes were obtained smoothly. A one-pot procedure of alkyne formation/Cu-mediated Huisgen cycloaddition was developed, which may find use in synthesizing natural product-based probes.

Graphical abstract: A mild preparation of alkynes from alkenyl triflates

  • This article is part of the themed collection: New Talent
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Publication details

The article was received on 12 Feb 2016, accepted on 15 Mar 2016 and first published on 15 Mar 2016


Article type: Communication
DOI: 10.1039/C6OB00345A
Citation: Org. Biomol. Chem., 2016,14, 5591-5594
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    A mild preparation of alkynes from alkenyl triflates

    X. Yang, D. Wu, Z. Lu, H. Sun and A. Li, Org. Biomol. Chem., 2016, 14, 5591
    DOI: 10.1039/C6OB00345A

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